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Soap bubble can freeze in winter because the air. temperature drops below the freezing point of the thin water layer that forms the bubble. When someone blows a bubble using a straw in extreme cold, the soap film cools almost instantly instead of popping as it normally would. As the temperature falls, water molecules inside the bubble begin to crystallize. Ice starts forming at a single point and then spreads across the surface in branching, feather-like patterns. These shapes appear because ice crystals grow along paths where freezing happens first, similar to how snowflakes form.
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